Pseudopterosins and Seco-Pseudopterosins: Compilation and Revision of Conflicting NMR Data, Names, Numbering Systems and Structural Elucidation

Autor:	Josep Coll toledano
Jazyk:	angličtina
Rok vydání:	2022
Předmět:	Pharmacology Structural elucidation Complementary and alternative medicine Terpenoids Serrulatane Drug Discovery Plant Science General Medicine NMR Pseudopterogorgia
Zdroj:	Digital.CSIC. Repositorio Institucional del CSIC instname
Popis:	The present review is focussed on the structural elucidation of the bicyclic and tricyclic diterpenoid title compounds isolated from Pseudopterogorgia species, displaying a direct structural relationship with the biosynthetic precursor GGPP (regular isoprenoid skeletons). A compilation of 1H and 13C NMR spectroscopic data is presented grouped by similar spin systems. Apparent inconsistencies or potential missassignments are discussed, pointing out convenient revisions of data assignment to improve structure correlations. Some hemisynthetic intermediates in the structural elucidation process are included, as well as data of representative synthetic compounds. The sending of requested copies of papers is gratefully acknowledged to Professors Athar Ata, Yoshinori Fujimoto and Dan Little, and useful answers and comments to Professor Carmenza Duque and Hebelin Correa.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e0f48be35a169ea55660e582d55874d5 http://hdl.handle.net/10261/267304 Zobrazit plný text záznamu