Crystal structure of 1-heptafluorotolyl-closo-1,2-dicarbadodecaborane
| Autor: | Hugo Tricas, Amanda Benton, Georgina M. Rosair, James D. Watson, Alan J. Welch |
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| Jazyk: | angličtina |
| Rok vydání: | 2019 |
| Předmět: |
crystal structure
Crystallography intramolecular F⋯H hydrogen-bond 010405 organic chemistry Hydrogen bond Aryl Substituent General Chemistry Crystal structure Borane 010402 general chemistry Condensed Matter Physics Ring (chemistry) 01 natural sciences Medicinal chemistry 0104 chemical sciences Research Communications chemistry.chemical_compound carborane intramolecular F...H hydrogen-bond chemistry QD901-999 Carborane General Materials Science |
| Zdroj: | Acta Crystallographica Section E: Crystallographic Communications Acta Crystallographica Section E: Crystallographic Communications, Vol 75, Iss 4, Pp 512-515 (2019) |
| ISSN: | 2056-9890 |
| Popis: | The title compound features an intramolecular hydrogen bond involving the acidic H atom bound to the cage C atom and an ortho-F atom of the heptafluorotolyl substituent. The molecular structure of the title compound 1-(2′,3′,5′,6′-tetrafluoro-4′-trifluoromethylphenyl)-closo-1,2-dicarbadodecaborane, C9H11B10F7, features an intramolecular ortho-F⋯H2 hydrogen bond [2.11 (2) Å], which is responsible for an orientation of the heptafluorotolyl substituent in which the plane of the aryl ring nearly eclipses the C1—C2 cage connectivity. |
| Databáze: | OpenAIRE |
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