Mechanistic inference on the roles of oxygenic functional groups that activate peroxymonosulfates in graphene for advanced oxidation

Autor: Xuechun Zhou, Gengping Wan, Guoqing Zhao, Maofan Zhou, Guizhen Wang
Rok vydání: 2022
Předmět:
Zdroj: Dalton transactions (Cambridge, England : 2003). 51(45)
ISSN: 1477-9234
Popis: Developing carbon-based catalysts for advanced oxidation processes, owing to their abundant reserves, metal-free properties, superior biocompatibility as well as great resistance to acids and alkalis, presents an enticing prospect for environmental remediation. The thermally reduced graphene with diverse surface functional groups from vacuum-promoting thermal expansion of graphene oxide was fabricated by the progressive carbonization from 250 °C to 1000 °C (denoted as G250, G600, and G1000 according to temperature). Among them, G1000 possessed highest defective degrees, the largest specific surface area, and the most abundant, highly active oxygen-containing functional groups such as ketones and quinones. 0.10 g L
Databáze: OpenAIRE