An Organic–Inorganic Hybrid Electrolyte as a Cathode Interlayer for Efficient Organic Solar Cells
| Autor: | Shengyong You, Binghui Wu, Zhang Yuefeng, Faming Han, Yonggang Wu, Chengyi Xiao, Zhou Zhang, Zhao Chaowei, Jie Fang, Dongdong Xia, Weiwei Li |
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| Rok vydání: | 2021 |
| Předmět: |
Organic electronics
Materials science Organic solar cell 010405 organic chemistry Energy conversion efficiency General Chemistry Electrolyte Conductivity 010402 general chemistry 01 natural sciences Catalysis Cathode 0104 chemical sciences law.invention Amorphous solid Chemical engineering law Thin film |
| Zdroj: | Angewandte Chemie International Edition. 60:8526-8531 |
| ISSN: | 1521-3773 1433-7851 |
| DOI: | 10.1002/anie.202100755 |
| Popis: | An organic-inorganic hybrid electrolyte based on a cyclic Ti-oxo cluster as the inorganic core and naphthalene-based organic ammonium bromide salts as the electrolyte was developed with easy synthesis and low cost. The new hybrid electrolyte exhibits excellent solubility in methanol, aligned work function, good conductivity, and amorphous state in thin film, enabling its successful application as a cathode interlayer in organic solar cells with a high power conversion efficiency of 17.19 %. This work demonstrates that the hybrid electrolytes are a new kind of semiconductor, exhibiting promising applications in organic electronics. |
| Databáze: | OpenAIRE |
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