Synthesis and Characterization of Benzodioxinone-Bearing Methacrylate-Based Random Copolymer via Atom Transfer Radical Polymerization
| Autor: | Gokhan Acik, Cumali Çelik |
|---|---|
| Přispěvatelé: | Açık, Gökhan |
| Jazyk: | angličtina |
| Rok vydání: | 2021 |
| Předmět: |
Bearing (mechanical)
Random copolymer Chemistry Atom-transfer radical-polymerization Atom transfer Polymer Science random copolymer General Chemistry Methacrylate Characterization (materials science) law.invention atom transfer radical polymerization Photochemical acylation law Radical polymerization Polymer chemistry Copolymer Polimer Bilimi photochemical acylation Ketene chemistry QD1-999 ketene chemistry Atom transfer radical polymerization ketene chemistry photochemical acylation random copolymer |
| Zdroj: | Volume: 8, Issue: 2 501-510 Journal of the Turkish Chemical Society Section A: Chemistry Journal of the Turkish Chemical Society, Section A: Chemistry, Vol 8, Iss 2, Pp 501-510 (2021) |
| ISSN: | 2149-0120 |
| Popis: | Methacrylate-benzodioxinone (BDMA) as a monomer was firstly synthesized and then copolymerized with methyl methacrylate and 2-hydroxyethyl methacrylate via atom transfer radical polymerization (ATRP) in the presence of CuCl/pentamethyldiethylene triamine (PMDETA) catalytic system using ethyl 2-bromopropionate (EtBrP) as an initiator. Successful formation of the block copolymer was also confirmed in detail by proton nuclear magnetic resonance spectroscopy (1H NMR), Fourier-transform infrared spectroscopy (FT-IR), and gel permeation chromatography (GPC) appropriately. Secondly, photochemical acylation of obtained copolymer through hydroxyl and benzodioxinone groups led to the release of benzophenone compound and ester-linkage on the polymer backbone. The formation of ester-linkage increases the glass transition temperature and the thermal stability of the obtained copolymer. © 2021, Turkish Chemical Society. All rights reserved. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|