On the ageing of high energy lithium-ion batteries-comprehensive electrochemical diffusivity studies of Harvested Nickel Manganese Cobalt Electrodes
| Autor: | Noshin Omar, Joris Jaguemont, Odile Capron, Rahul Gopalakrishnan, Joeri Van Mierlo, Peter Van Den Bossche |
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| Přispěvatelé: | Vrije Universiteit Brussel, Faculty of Engineering, Electromobility research centre, Electrical Engineering and Power Electronics, Industrial Sciences and Technology, Engineering Technology |
| Jazyk: | angličtina |
| Rok vydání: | 2018 |
| Předmět: |
Materials science
020209 energy Diffusion Analytical chemistry chemistry.chemical_element 02 engineering and technology Electrochemistry lcsh:Technology Article Electrochemical Impedance Spectroscopy Materials Science(all) 0202 electrical engineering electronic engineering information engineering General Materials Science lcsh:Microscopy lcsh:QC120-168.85 lcsh:QH201-278.5 lcsh:T 021001 nanoscience & nanotechnology Li diffusion coefficient Dielectric spectroscopy Atomic diffusion Nickel Ageing Li+ diffusion coefficient Nickel Manganese Cobalt ageing Cyclic Voltammetry Galvanostatic Intermittent Titration chemistry lcsh:TA1-2040 Lithium lcsh:Descriptive and experimental mechanics lcsh:Electrical engineering. Electronics. Nuclear engineering Cyclic voltammetry 0210 nano-technology lcsh:Engineering (General). Civil engineering (General) Cobalt lcsh:TK1-9971 |
| Zdroj: | Materials; Volume 11; Issue 2; Pages: 176 Materials, Vol 11, Iss 2, p 176 (2018) Materials |
| Popis: | This paper examines the impact of the characterisation technique considered for the determination of the L i + solid state diffusion coefficient in uncycled as in cycled Nickel Manganese Cobalt oxide (NMC) electrodes. As major characterisation techniques, Cyclic Voltammetry (CV), Galvanostatic Intermittent Titration Technique (GITT) and Electrochemical Impedance Spectroscopy (EIS) were systematically investigated. L i + diffusion coefficients during the lithiation process of the uncycled and cycled electrodes determined by CV at 3.71 V are shown to be equal to 3.48 × 10 − 10 cm 2 ·s − 1 and 1.56 × 10 − 10 cm 2 ·s − 1 , respectively. The dependency of the L i + diffusion with the lithium content in the electrodes is further studied in this paper with GITT and EIS. Diffusion coefficients calculated by GITT and EIS characterisations are shown to be in the range between 1.76 × 10 − 15 cm 2 ·s − 1 and 4.06 × 10 − 12 cm 2 ·s − 1 , while demonstrating the same decreasing trend with the lithiation process of the electrodes. For both electrode types, diffusion coefficients calculated by CV show greater values compared to those determined by GITT and EIS. With ageing, CV and EIS techniques lead to diffusion coefficients in the electrodes at 3.71 V that are decreasing, in contrast to GITT for which results indicate increasing diffusion coefficient. After long-term cycling, ratios of the diffusion coefficients determined by GITT compared to CV become more significant with an increase about 1 order of magnitude, while no significant variation is seen between the diffusion coefficients calculated from EIS in comparison to CV. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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