Self-assembly in the electrical double layer of ionic liquids
Autor: | Susan Perkin, Nitya Nand Gosvami, Heiko Niedermeyer, Tom Welton, Alexander M. Smith, Lorna Crowhurst |
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Jazyk: | angličtina |
Rok vydání: | 2016 |
Předmět: |
chemistry.chemical_classification
Chemistry Metals and Alloys Nanotechnology General Chemistry Chloride Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry.chemical_compound Hydrocarbon Chemical physics Monolayer Ionic liquid Materials Chemistry Ceramics and Composites medicine Mica Self-assembly Layering medicine.drug |
DOI: | 10.1039/c1cc11322d |
Popis: | We have studied the structure of two ionic liquids confined between negatively charged mica sheets. Both liquids exhibit interfacial layering, however the repeat distance is dramatically different for the two liquids. Our results suggest a transition from alternating cation-anion monolayers to tail-to-tail cation bilayers when the length of the cation hydrocarbon chain is increased. |
Databáze: | OpenAIRE |
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