Volatile components from European liverworts Marsupella emarginata, M. aquatica and M. alpina
| Autor: | Wilfried A. König, Hermann Muhle, Adewale M. Adio, Claudia Paul |
|---|---|
| Rok vydání: | 2002 |
| Předmět: |
chemistry.chemical_classification
Hepatophyta Magnetic Resonance Spectroscopy Plants Medicinal Molecular Structure Marsupella emarginata Stereochemistry Plant Science General Medicine Marsupella aquatica Horticulture Mass spectrometry Sesquiterpene Biochemistry Gas Chromatography-Mass Spectrometry Europe chemistry.chemical_compound Hydrocarbon chemistry Marsupella alpina Oils Volatile Gas chromatography Volatilization Molecular Biology |
| Zdroj: | Phytochemistry. 61(1) |
| ISSN: | 0031-9422 |
| Popis: | The hydrodistillation products of the liverworts Marsupella emarginata , M. aquatica and M. alpina were investigated by spectroscopic methods. A number of new compounds could be isolated by preparative gas chromatography (GC) and identified by spectroscopic techniques including GC-mass spectrometry, NMR and chemical correlations in conjunction with enantioselective GC. From M. emarginata , in addition to many known compounds, the sesquiterpene hydrocarbon (−)-7- epi -eremophila-1(10),8,11-triene ( 1 ) and the sesquiterpene derivatives (−)-4- epi -marsupellol ( 2 ), (−)-marsupellol acetate ( 18 ), (−)-4- epi -marsupellol acetate ( 4 ), (+)-5-hydroxymarsupellol acetate ( 5 ) and (−)-9-acetoxygymnomitr-8(12)-ene ( 24 ) could be identified. In M. aquatica the sesquiterpene hydrocarbons (−)-myltayl-8(12)-ene ( 7 ), ent -(+)-amorpha-4,11-diene ( 8 ), (−)-amorpha-4,7(11)-diene ( 9 ), the sesquiterpene alcohol (+)-9-hydroxyselina-4,11-diene ( 10 ) and (−)-2-acetoxyamorpha-4,7(11)-diene ( 11 ) were identified. In M. alpina (−)- trans -selina-4(15),11-dien-5-ol ( 12 ), (+)-8,9-epoxyselina-4,11-diene ( 13 ) and (+)- cis -selina-4(15),11-dien-5-ol ( 14 ) were found as new natural products. |
| Databáze: | OpenAIRE |
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