1-(5-Bromo-2-oxoindolin-3-ylidene)-4-phenylthiosemicarbazide

Autor:	Leandro Bresolin, Christian Näther, Adriano Bof de Oliveira, Katlen Crhistian Tribuzy Bandeira, Inke Jess
Rok vydání:	2013
Předmět:	Semicarbazide Hydrogen bond Stacking Thio General Chemistry Dihedral angle Condensed Matter Physics Ring (chemistry) Bioinformatics Organic Papers lcsh:Chemistry Crystallography chemistry.chemical_compound lcsh:QD1-999 chemistry General Materials Science
Zdroj:	Acta Crystallographica Section E, Vol 69, Iss 8, Pp o1337-o1338 (2013) Acta Crystallographica Section E: Structure Reports
ISSN:	1600-5368
DOI:	10.1107/s1600536813020497
Popis:	In the title compound, C15H11BrN4OS, the least-squares plane through the 5-bromoisatin fragment forms a dihedral angle of 13.63 (14)° with the phenyl ring. The molecular conformation features intramolecular N—H...N and N—H...O hydrogen bonds. In the crystal, molecules are connected via pairs of N—H...O interactions into centrosymmetric dimers. Additionally, π–π stacking interactions link molecules into chains parallel to the a axis with short C...C distances being observed between the phenyl and thiocarbonyl [3.236 (8) Å] groups and between the thiocarbonyl and carbonyl [3.351 (4) Å] groups of stacked molecules.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e01a6d99352bad5a11b2c99b2e2ba5f1 https://doi.org/10.1107/s1600536813020497 Zobrazit plný text záznamu