Morphology-dependent resonances in laser-induced fluorescence images of micrometric gasoline/ethanol droplets utilizing the dye nile red
| Autor: | Florian J. Bauer, Hongfei Dai, Mohammad Pahlevani Qomi, Lars Zigan, Bernd Eppinger, Matthias Koegl |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
Absorption (pharmacology)
endocrine system Materials science Ethanol business.industry Dispersity technology industry and agriculture Nile red Analytical chemistry 01 natural sciences Fluorescence Atomic and Molecular Physics and Optics 010309 optics chemistry.chemical_compound symbols.namesake Optics chemistry Stokes shift 0103 physical sciences symbols Electrical and Electronic Engineering Gasoline Laser-induced fluorescence business Engineering (miscellaneous) |
| Zdroj: | Applied optics. 60(17) |
| ISSN: | 1539-4522 |
| Popis: | The present study deals with the solvent-dependent morphology-dependent resonances (MDR) in the laser-induced fluorescence (LIF) signal of monodisperse gasoline droplets (30 µm–60 µm) generated with a droplet generator. To investigate the influence of an ethanol addition to gasoline and the respective LIF signal of the dye nile red dissolved in these fuel blends, a reference gasoline fuel is blended with various ethanol concentrations from E0 (gasoline) to E100 (pure ethanol). A spectral fluorescence characterization of the investigated fuel mixtures at various concentrations is carried out in a micro cell in order to identify the dye and ethanol concentration influence of the respective fuel mixtures. The absorption and emission spectra of the fuel mixtures show a Stokes shift with increasing ethanol concentration towards larger wavelengths. The coefficient of variation (COV) of the fluorescence signals of spherical droplets was utilized to characterize the MDR effects within the droplet LIF images. The investigations revealed an increase of MDR contribution in terms of the COV of LIF signals with larger droplet diameters. For small droplets, no monotonic trend was found for contribution of MDR in the LIF signal as a function of the ethanol concentration. For larger droplets (e.g., 50 µm–60 µm), a lower contribution of MDR in LIF signals was observed with increasing ethanol content. For E80 and most of the studied ethanol blends, the normalized integrated COV values exhibited maxima at certain droplet sizes (40 µm, 47.5 µm, and 55 µm), which indicate the presence of distinct MDR effects. |
| Databáze: | OpenAIRE |
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