A semi-flexible aminotriazine-based bis-methylpyridine ligand for the design of nickel(II) spin clusters

Autor:	Yen-Wen Tzeng, Motohiro Nakano, Chen-I Yang, Wun-Long Wan, Chang-Jui Lin, Long-Li Lai
Rok vydání:	2013
Předmět:	Ligand Inorganic chemistry chemistry.chemical_element law.invention Inorganic Chemistry chemistry.chemical_compound Crystallography Nickel chemistry law Azide Spin (physics) Electron paramagnetic resonance Ground state
Zdroj:	Dalton transactions (Cambridge, England : 2003). 43(8)
ISSN:	1477-9234
Popis:	The self-assembly of a semi-flexible aminotriazine-based bis-methylpyridine ligand, N(2),N(2)-dibenzyl-N(4),N(6)-di(pyridylmethyl)-1,3,5-triazine-2,4,6-triamine (H2L), with NiCl2 and NiBr2 afforded two new nickel(II) clusters, (H2NMe2)2[Ni5(OH)2(H2L)2Cl10] (1) and [Ni6(OH)2(H2L)2Br10(THF)2] (2) showing a high spin ground state of S = 3.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::dfbbf83e1dd877c5472eee9d16ef4008 https://pubmed.ncbi.nlm.nih.gov/24264831 Zobrazit plný text záznamu