Orthogonalization of Polyaryl Linkers as a Route to More Porous Phosphonate Metal‐Organic Frameworks

Autor:	Martin Glavinović, Justin H. Perras, Benjamin S. Gelfand, Jian‐Bin Lin, George K. H. Shimizu
Rok vydání:	2022
Předmět:	Metals Organic Chemistry Organophosphonates General Chemistry Ligands Porosity Metal-Organic Frameworks Catalysis
Zdroj:	Chemistry – A European Journal. 28
ISSN:	1521-3765 0947-6539
DOI:	10.1002/chem.202200874
Popis:	The coordinative pliancy of the phosphonate functional group means that metal-phosphonate materials often self-assemble as well-packed structures with minimal porosity, as efficient inter-ligand packing is enabled. Here, we report a multistep synthesis of a novel aryl-phosphonate linker with an orthogonalized ligand core, 1,3,5-tris(4'-phosphonophenyl)-2,4,6-trimethylbenzene (H
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::df507fd00db2bd71f5adc248241392e8 https://doi.org/10.1002/chem.202200874 Zobrazit plný text záznamu