Metallo-Supramolecular Coordination Polymers Based on Amidopyridine Derivatives of Pillar[5]arene and Cu(II) and Pd(II) Cations: Synthesis and Recognition of Nitroaromatic Compounds
| Autor: | Marat Gafurov, Gennady Evtugyn, D. N. Shurpik, Yurii I. Kuzin, Vladimir G. Evtugyn, Yulia I. Aleksandrova, I. R. Vakhitov, Alexander V. Gerasimov, Alexander Rodionov, Ivan I. Stoikov, Elena A. Razina, Peter J. Cragg |
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| Rok vydání: | 2021 |
| Předmět: |
chemistry.chemical_classification
Aqueous solution Scanning electron microscope Supramolecular chemistry 02 engineering and technology Surfaces and Interfaces Polymer 010402 general chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics 01 natural sciences 0104 chemical sciences Amorphous solid Electrochemical gas sensor chemistry.chemical_compound chemistry Dynamic light scattering Polymer chemistry Electrochemistry General Materials Science Methanol 0210 nano-technology Spectroscopy |
| Zdroj: | Langmuir : the ACS journal of surfaces and colloids. 37(9) |
| ISSN: | 1520-5827 |
| Popis: | Decasubstituted pillar[5]arenes containing amidopyridine fragments have been synthesized for the first time. As was shown by UV-vis spectroscopy, the pillar[5]arenes with p-amidopyridine fragments form supramolecular associates with Cu(II) and Pd(II) cations in methanol in a 2:1 ratio. Using a sol-gel approach these associates are transformed into metallo-supramolecular coordination polymers (supramolecular gels) which were characterized as amorphous powders by scanning electron microscopy (SEM) and dynamic light scattering (DLS). The powders are able to selectively adsorb up to 46% of nitrophenols from water and were incorporated into an electrochemical sensor to selectively recognize them in aqueous acidic solution. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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