Direct laser writing of visible and near infrared 3D luminescence patterns in glass

Autor: Alassani, Fouad, Galleani, Gustavo, Raffy, Guillaume, Guerzo, André Del, Royon, Arnaud, Bourhis, Kevin, de Camargo, Andrea Simone Stucchi, Jubera, Veronique, Canioni, Lionel, Cardinal, Thierry, Petit, Yannick
Přispěvatelé: Institut de Chimie de la Matière Condensée de Bordeaux (ICMCB), Université de Bordeaux (UB)-Institut Polytechnique de Bordeaux-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Universidade de São Paulo = University of São Paulo (USP), Institut des Sciences Moléculaires (ISM), Université Montesquieu - Bordeaux 4-Université Sciences et Technologies - Bordeaux 1 (UB)-École Nationale Supérieure de Chimie et de Physique de Bordeaux (ENSCPB)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Argolight S.A., Centre d'Etudes Lasers Intenses et Applications (CELIA), Université de Bordeaux (UB)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Centre National de la Recherche Scientifique (CNRS), This project has received support funding from GPR IDEX Bordeaux and French National Research Agency (ANR) ANR- 21-PRRD-0001-01/PDR- Stabilo., The Brazilian team would like to acknowledge funding from FAPESP – Fundação de Amparo a Pesquisa do Estado de São Paulo, through the CeRTEV project N. 2013/07793-6., FAPESP for the Postdoctoral scholarship N. 2018/03931-9., ANR-19-CE08-0021,ArchiFLUO,Architectures photoniques intégrées inscrites par laser femtoseconde pour étalonnage en microscopie de fluorescence dans l'infrarouge(2019)
Rok vydání: 2022
Předmět:
Zdroj: Repositório Institucional da USP (Biblioteca Digital da Produção Intelectual)
Universidade de São Paulo (USP)
instacron:USP
Optical Materials: X
Optical Materials: X, 2022, 16, 100205 (10 p.). ⟨10.1016/j.omx.2022.100205⟩
ISSN: 2590-1478
DOI: 10.1016/j.omx.2022.100205⟩
Popis: International audience; We report the fluorescent properties of 3D localized structure with size near the diffraction limit induced by femtosecond direct laser writing (DLW) in Yb 3+ and silver-containing phosphate glass. The homogenous dispersion of the silver ions and Yb 3+ ions in the glass matrix before DLW was evidenced using photo-luminescent spectroscopy and time-resolved spectroscopy. Using high repetition rate femtosecond DLW, the inscription of 3D visible and near-infrared fluorescent patterns formed by co-localization of silver cluster and Yb 3+ ions was demonstrated. The local refractive index change associated with the formation of silver clusters is dependent on the laser irradiance. Confocal micro-luminescent spectroscopy for excitation wavelength in the visible range shows efficient emission of Yb 3+ only on DLW induced 3D fluorescent patterns. This finding demonstrated the ability to perform thanks to DLW laser a resonant efficient nonradiative energy transfer from silver clusters to Yb 3+ and allows 3D writing of near-infrared luminescence.
Databáze: OpenAIRE