Metal–Organic Nanogel with Sulfonated Three-Dimensional Continuous Channels as a Proton Conductor

Autor: Xunli Mao, Pengfei Yang, Haobo Geng, Zhongyi Jiang, Xueyi He, Ming Qiu, Hong Wu, Li Cao, Benbing Shi
Rok vydání: 2020
Předmět:
Zdroj: ACS Applied Materials & Interfaces. 12:19788-19796
ISSN: 1944-8252
1944-8244
DOI: 10.1021/acsami.0c02048
Popis: Developing novel proton conductors is crucial to the electrochemical technology for energy conversion and storage. Metal-organic frameworks (MOFs), with a highly ordered and controllable structure, have been widely explored to prepare high-performance proton conductors. Albeit the prominent merits and great potential of the MOF-based materials such as MOF pellets or composite polymer electrolytes, constructing well-defined proton-transfer channels with much lower grain boundary resistance and more homogeneous distribution deserves extensive explorations. Herein, a kind of nanostructured metal-organic gel (MOG) with a three-dimensional (3D) interconnected proton-conductive network is prepared by a facile sol-gel method using Cr
Databáze: OpenAIRE