Biopolymer blends from hardwood lignin and bio-polyamides: Compatibility and miscibility
| Autor: | Baljinder K. Kandola, A.R. Horrocks, M. Hajee, Rajendran Muthuraj |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
Thermogravimetric analysis
02 engineering and technology engineering.material Lignin Biochemistry Miscibility Phase Transition 03 medical and health sciences chemistry.chemical_compound Structural Biology Materials Testing Particle Size Fourier transform infrared spectroscopy Molecular Biology 030304 developmental biology 0303 health sciences Viscosity Compatibility (geochemistry) General Medicine 021001 nanoscience & nanotechnology Wood Nylons chemistry Chemical engineering Polyamide engineering Thermodynamics Biopolymer Crystallization Rheology 0210 nano-technology Glass transition |
| Zdroj: | International Journal of Biological Macromolecules |
| ISSN: | 0141-8130 |
| DOI: | 10.1016/j.ijbiomac.2019.03.142 |
| Popis: | The compatibility of hardwood lignin (TcA)/bio-polyamide (PA) blends, prepared by melt compounding TcA with three different biobased polyamides, PA 1012, PA 1010 and PA 11 in a twin screw extruder has been studied. FTIR studies indicated the existence of physicochemical interactions between the TcA and polyamide. The melting temperatures of the blends were significantly reduced compared to the respective neat polyamides, which was attributed to the enhanced compatibility between the two components. The compatibility was also attributed to the increased glass transition (Tg) of the polyamide. Thermogravimetric studies, while not indicating any interaction during the processing stage, suggested that there was some during the thermal degradation stage, which assisted formation of carbonaceous residue. The addition of each polyamide to TcA considerably reduced its viscosity and enhanced its processability even at high lignin contents. Morphological analysis showed that heterogeneity for all the blends was quite uniform, although TcA domain sizes were considerably smaller (~0.5 μm) in the PA11 matrix compared to those in PA1010 and PA1012, suggesting better compatibility in the TcA/PA11 blends. This observation was consistent with the thermodynamic Gibbs' free energy values of the respective blends. Overall, the order of blend compatibility was TcA/PA11 > TcA/PA1010 > TcA/PA1012. |
| Databáze: | OpenAIRE |
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