Diboron reagents in the deoxygenation of nitrones

Autor: Emily L. Vargas, Mario Franco, Inés Alonso, Mariola Tortosa, M. Belén Cid
Rok vydání: 2023
Předmět:
Zdroj: Organic & Biomolecular Chemistry. 21:807-816
ISSN: 1477-0539
1477-0520
Popis: B2nep2 efficiently cleaves the N–O bond of nitrones through a concerted mechanism to form imines in very high yields via a simple, efficient and scalable protocol. Typical radical traps like DMPO and TEMPO are also deoxygenated by diboron reagents.
Databáze: OpenAIRE