Formation of PPh2C6F5 through phosphido platinum and/or palladium(III) intermediates
| Autor: | Athanassios C. Tsipis, Irene Ara, Naima Chaouche, Consuelo Fortuño, Juan Forniés, and Abdelaziz Kribii |
|---|---|
| Rok vydání: | 2006 |
| Předmět: |
palladium(ii)-platinum(ii) pentafluorophenyl complexes
molecular-structure bu-t Stereochemistry Organic Chemistry chemistry.chemical_element stereoselective oxidative addition Medicinal chemistry Redox Inorganic Chemistry ray crystal-structures c bond chemistry bridging diphenylphosphido ligands pd-c6f5 bonds electronic-structures Physical and Theoretical Chemistry Platinum density-functional theory Palladium |
| Zdroj: | Digital.CSIC. Repositorio Institucional del CSIC instname |
| Popis: | 8 pages, 5 figures, 3 tables. The two-electron oxidation reactions of the neutral [(C6F5)2M(μ-PR2)2M‘(NCCH3)2] (M = M‘ = Pt or Pd, M = Pt, M‘ = Pd) complexes using I2 as oxidant have been investigated by experimental (R = Ph) and electronic structure calculation methods (R = H). It was found that a reductive coupling of PR2 and C6F5 takes place along the reaction pathway for all oxidized complexes. The most salient structural features of the [(C6F5)2Pt(μ-PR2)2Pd(C6F5)2]2-, [(C6F5)2Pd(μ-PR2)2Pd(acac)]-, and [(C6F5)2Pt(μ-PR2)2PtI2] complexes (experimental R = Ph) are reproduced very well by the B3LYP/lanl2dz calculations (R = H). We thank the Ministerio de Ciencia y Tecnología and Fondos FEDER (Project BQU2002-03997-CO2- 02), the Diputación General de Aragón for its financial support, and the Agencia Española de Cooperación Internacional (Ministerio de Asuntos Exteriores) for a grant to N.Ch. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|