New oleanane-type triterpenoid saponins isolated from the seeds ofCelosia argentea
Autor: | Xin-Tong Fu, Hai-Xia Yan, Yang Zhao, Bai-Ping Ma, Cheng-Qi Xiong, Hong-Zhu Guo, Zhen-Fang Wang, Fan Miaoxuan, Jie Zhang, Xu Pang |
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Rok vydání: | 2014 |
Předmět: |
Pharmacology
Molecular Structure biology Stereochemistry Organic Chemistry Pharmaceutical Science Stereoisomerism General Medicine Saponins biology.organism_classification Celosia Analytical Chemistry chemistry.chemical_compound Triterpenoid Chemical marker Complementary and alternative medicine chemistry Seeds Drug Discovery Molecular Medicine Oleanolic Acid Nuclear Magnetic Resonance Biomolecular Oleanane Celosia argentea Drugs Chinese Herbal |
Zdroj: | Journal of Asian Natural Products Research. 16:240-247 |
ISSN: | 1477-2213 1028-6020 |
Popis: | Three new oleanane-type triterpenoid saponins named celosins H (1), I (2), and J (3) were isolated from the seeds of Celosia argentea L. Their structures were characterized as 3-O-β-d-xylopyranosyl-(1 → 3)-β-d-glucuronopyranosyl-polygalagenin 28-O-β-d-glucopyranosyl ester, 3-O-β-d-glucuronopyranosyl-medicagenic acid 28-O-β-d-xylcopyranosyl-(1 → 4)-α-l-rhamnopyranosyl-(1 → 2)-β-d-fucopyranosyl ester, and 3-O-β-d-glucuronopyranosyl-medicagenic acid 28-O-α-l-arabinopyranosyl-(1 → 3)-[β-d-xylcopyranosyl-(1 → 4)]-α-l-rhamnopyranosyl-(1 → 2)-β-d-fucopyranosyl ester by NMR, MS, and chemical evidences, respectively. In our opinion, celosins H–J could be used as chemical markers for the quality control of C. argentea seeds. |
Databáze: | OpenAIRE |
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