Effects of Covalency on Anionic Redox Chemistry in Semiquinoid-Based Metal-Organic Frameworks

Autor: Won Ryu, Carlo Alberto Gaggioli, Laura Gagliardi, Ari Turkiewicz, Michael E. Ziebel, Jeffrey R. Long
Rok vydání: 2020
Předmět:
Zdroj: Journal of the American Chemical Society. 142(5)
ISSN: 1520-5126
Popis: Two iron–semiquinoid framework materials, (H2NMe2)2Fe2(Cl2 dhbq)3 (1) and (H2NMe2)4Fe3(Cl2 dhbq)3(SO4)2 (Cl2 dhbqn– = deprotonated 2,5-dichloro-3,6-dihydroxybenzoquinone) (2-SO4), are shown to poss...
Databáze: OpenAIRE