Modelling three-way catalytic converter oriented to engine cold-start conditions

Autor: Christopher H. Onder, Benjamín Pla, Raffael Hedinger, Marcelo Real
Rok vydání: 2019
Předmět:
Zdroj: RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
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ISSN: 2041-3149
1468-0874
DOI: 10.1177/1468087419853145
Popis: This article introduces a physical model of a three-way catalytic converter oriented to engine cold-start conditions. Computational cost is an important factor, particularly when the modelling is oriented to the development of engine control strategies. That is why a one-dimensional one-channel real-time capable model is proposed. The present model accounts for two phases, gas and solid, respectively, considering not only the heat transfer by convection between both, but also the water vapour condensation and evaporation in the catalyst brick, which plays a key role during engine cold-start. Moreover, the model addresses the conductive heat flow, heat losses to the environment and exothermic reactions in the solid phase, as well as the convective heat flow in the gas phase. Regarding the chemical model, the oxidation of hydrocarbons and carbon monoxide is considered by means of the Langmuir–Hinshelwood mechanism. Three layers make up the model structure from a kinetic point of view, bulk gas, washcoat pores and noble metal in the catalyst surface. The model takes fuel-to-air ratio, exhaust gas mass flow, temperature, pressure and gas composition as inputs, providing the thermal distribution as well as the species concentration along the converter.
Databáze: OpenAIRE