Tin(IV) Chalcogenide Complexes: Single Source Precursors for SnS, SnSe and SnTe Nanoparticle Synthesis
| Autor: | Andrew L. Johnson, Joseph R. Thompson, Gabriele Kociok-Köhn, Ibbi Y. Ahmet |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
Solid-state chemistry
Thermogravimetric analysis Tin Chalcogenides 010405 organic chemistry Chalcogenide Inorganic chemistry Precursors chemistry.chemical_element Nanoparticle X ray crystallography Nuclear magnetic resonance spectroscopy 010402 general chemistry materials chemistry 01 natural sciences 0104 chemical sciences Inorganic Chemistry Synthesis chemistry.chemical_compound Crystallography chemistry X-ray crystallography Nanoparticles Tin Single crystal |
| Zdroj: | Johnson, A, Thompson, J, Ahmet, I & Kociok-Kohn, G 2016, ' Tin(IV) chalcogenide complexes : single source precursors for SnS, SnSe and SnTe nanoparticle synthesis ', European Journal of Inorganic Chemistry, vol. 2016, no. 28, pp. 4711-4720 . https://doi.org/10.1002/ejic.201600790 |
| ISSN: | 1099-0682 1434-1948 |
| DOI: | 10.1002/ejic.201600790 |
| Popis: | A family of tin(IV) bis(hexamethylsilylamide) complexes 2–9 have been synthesized by reaction of [Sn{N(SiMe3)2}2] (1) with the diphenyl dichalcogenanes Ph2E2 (E = S, Se, Te), the radical species TEMPO, or the group 16 elements to form the complexes [(PhE)2Sn{N(SiMe3)2}2] (2–4) and [(TEMPO)2Sn{N(SiMe3)2}2] (5), and [{(Me3Si)2N}2Sn(µ2-E)]2 (6–9) (E = S, 2 & 6; E = Se 3 & 7; E = Te, 4 & 9, E = O2, 9). The isolated tin complexes were characterized by elemental analysis, NMR spectroscopy, and the molecular structures of the complexes were determined by single crystal X-ray diffraction. Thermogravimetric analysis showed complexes 2–4 and 6–8 all to have residual masses close to those expected for the formation of the corresponding “SnE” systems. Complexes 2–4 and 6–8 were also assessed for their utility in the formation of nanoparticles. The materials obtained were characterized by powder X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM) and energy-dispersive X-ray analysis (EDX). Analysis showed formation of SnSe and SnTe from complexes 3–4 and 6–7, respectively. |
| Databáze: | OpenAIRE |
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