Facile synthesis of nanostructured cobalt pigments by Co- A zeolite thermal conversion and its application in porcelain manufacture
| Autor: | Domenico Caputo, Gennaro Cavaliere, Valter Luca De Bartolomeis, Barbara Liguori, Ottavio Marino, Assunta Campanile |
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| Přispěvatelé: | Campanile, A., Liguori, B., Marino, O., Cavaliere, G., De Bartolomeis, V. L., Caputo, D. |
| Rok vydání: | 2020 |
| Předmět: |
Materials science
lcsh:Medicine chemistry.chemical_element 02 engineering and technology Raw material 010402 general chemistry 01 natural sciences Article Pigment Thermal Structure of solids and liquids Inorganic pigments lcsh:Science Zeolite Multidisciplinary Ion exchange lcsh:R Synthesis and processing 021001 nanoscience & nanotechnology 0104 chemical sciences chemistry Colored Chemical engineering visual_art visual_art.visual_art_medium lcsh:Q 0210 nano-technology Cobalt |
| Zdroj: | Scientific Reports Scientific Reports, Vol 10, Iss 1, Pp 1-9 (2020) |
| ISSN: | 2045-2322 |
| Popis: | An innovative and facile synthesis of cobalt based inorganic pigment was carried out by means of a low energy thermal conversion of a cobalt-exchanged zeolite. The Na-A [LTA] zeolite was used, since it is a low cost and easily available raw material. The ion exchange mechanism allowed to control, at microscopic level, the composition of the zeolitic precursor. Several chromatic effects could be obtained by varying the treatment temperature and/or the cobalt concentration in the contact solution. The reliability of these new zeolite-based pigments was tested in porcelain manufacture, in collaboration with the Institute for the Capodimonte porcelain “Giovanni Caselli”. The developed cobalt pigments were successfully tested either in the porcelain mixture to obtain a coloured product or in the decoration step (such as ingobbio, colored glazes and “third fire decoration”). |
| Databáze: | OpenAIRE |
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