Magnetic structures of Fe32+δGe33As2 and Fe32+δ′Ge35−xPx intermetallic compounds: a neutron diffraction and 57Fe Mössbauer spectroscopy study
| Autor: | Alexey V. Sobolev, Françoise Damay, Andrei V. Shevelkov, Igor A. Presniakov, Roman A. Khalaniya, Anatoliy Senyshyn, V. Yu. Verchenko, Alexander A. Tsirlin |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
Materials science
Magnetic moment Condensed matter physics Neutron diffraction Intermetallic 02 engineering and technology Crystal structure 021001 nanoscience & nanotechnology 01 natural sciences Magnetic field Inorganic Chemistry 0103 physical sciences Mössbauer spectroscopy Condensed Matter::Strongly Correlated Electrons 010306 general physics 0210 nano-technology Spin (physics) Hyperfine structure |
| Zdroj: | Dalton Transactions. 50:2210-2220 |
| ISSN: | 1477-9234 1477-9226 |
| DOI: | 10.1039/d0dt03923c |
| Popis: | Fe32+δGe33As2 and Fe32+δ′Ge35−xPx are quasi-binary intermetallic compounds that possess a rare variant of intergrowth-type crystal structure, which is a combination of the column shaped Co2Al5 and MgFe6Ge6 structure type blocks. The compounds are antiferromagnets with the Neel temperatures around 125 K. Neutron powder diffraction experiments on the samples with δ ≈ 0.1, δ′ ≈ 0.5 and x ≈ 3 reveal commensurate magnetic ordering of low symmetry in both compounds and a non-monotonic change in the intensities of magnetic reflections. On the other hand, temperature dependence of the hyperfine fields obtained from 57Fe Mossbauer spectroscopy indicates a gradual, monotonic increase in local magnetic fields upon cooling. We interpret these results as a spin reorientation within the Co2Al5-type block of the crystal structure, with the possible formation of a non-collinear magnetic order at low temperatures. Between the compounds, the reorientation occurs at significantly different temperatures, however the resulting magnetic structures themselves are similar as well as the average values of the magnetic moments and the hyperfine fields. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|