Fillers as Heaters for Photothermal Polymerization upon NIR Light
| Autor: | Frédéric Dumur, Jean Pierre Fouassier, Jacques Lalevée, Aude Héloïse Bonardi, Fabrice Bonardi, Didier Gigmes |
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| Přispěvatelé: | Institut de Science des Matériaux de Mulhouse (IS2M), Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Matériaux et Nanosciences Grand-Est (MNGE), Université de Strasbourg (UNISTRA)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Institut National de la Santé et de la Recherche Médicale (INSERM)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Université de Strasbourg (UNISTRA)-Institut National de la Santé et de la Recherche Médicale (INSERM)-Centre National de la Recherche Scientifique (CNRS)-Réseau nanophotonique et optique, Université de Strasbourg (UNISTRA)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Centre National de la Recherche Scientifique (CNRS)-Université de Strasbourg (UNISTRA)-Centre National de la Recherche Scientifique (CNRS), Institut de Chimie Radicalaire (ICR), Aix Marseille Université (AMU)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Aix Marseille Université (AMU), Gigmes, Didier, Centre National de la Recherche Scientifique (CNRS)-Matériaux et nanosciences d'Alsace (FMNGE), Institut de Chimie du CNRS (INC)-Université de Strasbourg (UNISTRA)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Institut National de la Santé et de la Recherche Médicale (INSERM)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Strasbourg (UNISTRA)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Institut National de la Santé et de la Recherche Médicale (INSERM)-Centre National de la Recherche Scientifique (CNRS)-Réseau nanophotonique et optique, Centre National de la Recherche Scientifique (CNRS)-Université de Strasbourg (UNISTRA)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Centre National de la Recherche Scientifique (CNRS)-Université de Strasbourg (UNISTRA) |
| Rok vydání: | 2019 |
| Předmět: |
Materials science
Polymers and Plastics Infrared Rays Carbon Compounds Inorganic 02 engineering and technology Carbon nanotube 010402 general chemistry 01 natural sciences Polymerization law.invention law Materials Testing [CHIM] Chemical Sciences Materials Chemistry [CHIM]Chemical Sciences Curing (chemistry) Nanotubes Carbon Graphene Silicon Compounds Organic Chemistry Photothermal effect Temperature Photothermal therapy Photochemical Processes 021001 nanoscience & nanotechnology 0104 chemical sciences Photopolymer Chemical engineering Graphite 0210 nano-technology Visible spectrum |
| Zdroj: | Macromolecular Rapid Communications Macromolecular Rapid Communications, 2019, pp.1900495. ⟨10.1002/marc.201900495⟩ |
| ISSN: | 1521-3927 1022-1336 |
| Popis: | WOS:000493163500001; International audience; Photo-induced thermal polymerization upon near-infrared (NIR) light irradiation has been reported in the literature. In this approach, a component able to convert the NIR light into heat must be used in combination with a thermal initiator to initiate the free-radical polymerization of (meth)acrylates. In recent studies, some absorbers have been presented as very efficient heat generators (called heaters). In the present work, different fillers are investigated as heaters and compared to organic NIR absorbers. An alkoxyamine (e.g., BlocBuilder-MA) is used as thermal initiator and is dissociated by the heat generated by the NIR photoexcitation of the fillers. In the present work, several fillers are examined: graphene oxide, graphene nanoplatelets, multi-walled carbon nanotubes, and silicon carbide. Due to the energy of the photon delivered, NIR light curing is challenging but offers several advantages compared to visible light. The most interesting feature is the deeper penetration of the light inside the photocurable resin, enabling the polymerization of thick samples. Parallel to this, incorporation of fillers in resins allows unique access to composites through photothermal polymerization of (meth)acrylates. Three different wavelengths of irradiation have been studied: 785, 940, and 1064 nm. |
| Databáze: | OpenAIRE |
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