EVIDENCE FOR THE CHEMICAL NATURE AND ORDERING OF COBALTOCENE INTERCALATED IN CDPS3 USING SINGLE-CRYSTAL SOLID-STATE H-2 NMR-SPECTROSCOPY

Autor:	Dermot O'Hare, Stephen J. Heyes, Susan J. Mason
Rok vydání:	2016
Předmět:	NMR spectra database chemistry.chemical_compound Crystallography chemistry Lattice (order) Cobaltocene Solid-state Molecular Medicine Molecule Nuclear magnetic resonance spectroscopy Single crystal Metallocene
DOI:	10.1039/c39950001657
Popis:	Solid state 2H NMR spectra of single crystal samples of CdPS3{Co(η-C5D5)2}0.4 indicate the co-existence of both Co(η-C5D5)2 and [Co(η-C5D5)2]+between the CdPS3layers; all the metallocene guest molecules reside in ordered domains within the ab-plane of the host lattice at a 90° angle to each other, and with their principal C5-symmetry axes parallel to the layers of the host lattice.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::dc00870996d9998e1f48f28b3098eeb6 https://doi.org/10.1039/c39950001657 Zobrazit plný text záznamu