Solid-state porphyrin interactions with oppositely charged peripheral groups

Autor:	Scheidt Wr, Beisong Cheng, Allen G. Oliver, Goodwin Ja
Rok vydání:	2015
Předmět:	010405 organic chemistry Solid-state General Chemistry 010402 general chemistry Electrostatics Photochemistry 01 natural sciences Porphyrin Article 0104 chemical sciences law.invention Crystal chemistry.chemical_compound Crystallography chemistry law Molecule Pi interaction Crystallization
Zdroj:	Journal of Porphyrins and Phthalocyanines. 19:1256-1261
ISSN:	1099-1409 1088-4246
DOI:	10.1142/s1088424615501084
Popis:	The crystallization and the crystal and molecular structure of a very slightly soluble electrostatically interacting pair of porphyrins is described. The tetra-anion 5,10,15,20-tetrakis-(4-sulfonatophenyl)-21,23H-porphyrin [H2TPPSO3][Formula: see text] and the tetra-cation 5,10,15,20-tetra([Formula: see text]-methylpyridyl)21H,23H-porphyrin [H2TMePyP][Formula: see text] are found to form an alternating one-dimensional stack that is stabilized by electrostatic interactions between the porphyrin rings but also by [Formula: see text] interactions between all substituted phenyl rings in the ensemble. The resulting interactions between the porphyrins is exceptionally tight.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::dbc44f83d53e05f77be0a0c20e5327de https://doi.org/10.1142/s1088424615501084 Zobrazit plný text záznamu