Reactivity of [Pt(PtBu3)2] with Zinc(I/II) Compounds: Bimetallic Adducts, Zn–Zn Bond Cleavage, and Cooperative Reactivity
| Autor: | Israel Fernández, Carlos Romero-Pérez, Celia Maya, Nereida Hidalgo, Jesús Campos |
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| Přispěvatelé: | European Research Council, Ministerio de Ciencia e Innovación (España), Universidad de Sevilla. Departamento de Química Inorgánica, European Research Council (ERC), Ministerio de Ciencia e Innovación (MICIN). España |
| Rok vydání: | 2021 |
| Předmět: |
Steric effects
010405 organic chemistry Negishi coupling Organic Chemistry chemistry.chemical_element Zinc 010402 general chemistry 01 natural sciences Medicinal chemistry 0104 chemical sciences 3. Good health Inorganic Chemistry chemistry Transition metal Electrophile Reactivity (chemistry) Physical and Theoretical Chemistry Bimetallic strip Bond cleavage |
| Zdroj: | Digital.CSIC. Repositorio Institucional del CSIC instname |
| Popis: | Metal-only Lewis pairs (MOLPs) based on zinc electrophiles are particularly interesting due to their relevance to Negishi cross-coupling reactions. Zinc-based ligands in bimetallic complexes also render unique reactivity to the transition metals at which they are bound. Here we explore the use of sterically hindered [Pt(PtBu3)2] (1) to access Pt/Zn bimetallic complexes. Compounds [(PtBu3)2Pt→Zn(C6F5)2] (2) and [Pt(ZnCp*)6] (3) (Cp* = pentamethylcyclopentadienyl) were isolated by reactions with Zn(C6F5)2 and [Zn2Cp*2], respectively. We also disclose the cooperative reactivity of 1/ZnX2 pairs (X = Cl, Br, I, OTf) towards water and dihydrogen, which can be understood in terms of bimetallic frustration |
| Databáze: | OpenAIRE |
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