Palladium(II)-Catalyzed γ-Selective Hydroarylation of Alkenyl Carbonyl Compounds with Arylboronic Acids

Autor: Rei Matsuura, Tanner Jankins, Kin Yang, Gary Gallego, Shouliang Yang, Mingying He, Fen Wang, Rohan Marsters, Indrawan McAlpine, Keary Engle
Rok vydání: 2018
DOI: 10.26434/chemrxiv.6148124
Popis: A catalytic γ-selective syn-hydroarylation of alkenyl carbonyl compounds using arylboronic acids has been developed using a substrate directivity approach with a palladium(II) catalyst. This method tolerates a wide range of functionalized (hetero)arylboronic acids and a variety of substitution patterns on the alkene.
Databáze: OpenAIRE