Photo-switchable anion binding and catalysis with a visible light responsive halogen bonding receptor

Autor:	Aidan Kerckhoffs, Isabelle Moss, Matthew J. Langton
Rok vydání:	2022
Předmět:	Materials Chemistry Metals and Alloys Ceramics and Composites General Chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials
Zdroj:	Chemical communications (Cambridge, England).
ISSN:	1364-548X
Popis:	Photo-switchable receptors allow for photo-control over guest binding and release with spatial and temporal precision. Here we report the first halogen bonding photo-switchable anion receptors in which chloride binding may be reversibly modulated by irradiation with red and blue light, with over a 50-fold enhancement in chloride binding affinity observed for the Z isomer. We demonstrate that this switchable binding enables unprecedented photo-controlled catalysis of XB-mediated halide abstractions and a Mukaiyama Aldol reaction.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::dac1271a0b72543ac041b1d3c2f02783 https://pubmed.ncbi.nlm.nih.gov/36440635 Zobrazit plný text záznamu