A Quinazolinone based fluorescent chemosensor for selective detection of Fe(III) in aqueous media: Applications to pharmaceutical and environmental analysis
| Autor: | Anil H. Gore, Uttam R. Kondekar, Balu D. Ajalkar, Govind B. Kolekar, Pravin R. Dongare |
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| Rok vydání: | 2017 |
| Předmět: |
Detection limit
Aqueous medium Environmental analysis 010405 organic chemistry Chemistry Metal ions in aqueous solution Inorganic chemistry Analytical chemistry 010402 general chemistry 01 natural sciences Fluorescence 0104 chemical sciences Ion Inorganic Chemistry chemistry.chemical_compound Physical and Theoretical Chemistry Selectivity Quinazolinone |
| DOI: | 10.6084/m9.figshare.5330614.v1 |
| Popis: | A Quinazolinone based chemosensor 2-(1,3-thiazol-2-yl)-2,3-dihydroquinazolin-4(1 H)-one (1) has been synthesized, that exhibits high sensitivity and selectivity for Fe3+ over other environmentally and biologically relevant metal ions by the changes in fluorescence properties and reversible with the addition of EDTA. Under the optimized conditions, Stern-Volmer plot gives a good relationship between chemosensor 1 and Fe3+ with detection limit 0.0366 µg.mL−1. The binding mode of 1 toward Fe3+ has been investigated by Job's plot, Benesi-Hildebrand plot, FTIR spectra measurements and theoretically supported by DFT calculations. Moreover, the sensor was successfully `applied for quantitative determination of Fe3+ ions in pharmaceutical and water sample. |
| Databáze: | OpenAIRE |
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