A Sterically-Encumbered, C2-Symmetric Chiral Acetal for Enhanced Asymmetric Induction in the Pauson−Khand Reaction

Autor:	Chitaru Hirosawa, Llorente V. R. Bonaga, Sean Kerrigan, Marie E. Krafft, Andrew S. Felts
Rok vydání:	2003
Předmět:	Diketone chemistry.chemical_classification Steric effects chemistry.chemical_compound Ketone Stereochemistry Chemistry Pauson–Khand reaction Organic Chemistry Acetal Asymmetric induction Chemical synthesis
Zdroj:	The Journal of Organic Chemistry. 68:6039-6042
ISSN:	1520-6904 0022-3263
DOI:	10.1021/jo0263667
Popis:	High levels of diastereoselection were achieved in the PKR of 1,6- and 1,7-cyclopropylidenynes bearing a bulky propargylic C(2)-symmetric acetal.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::da8665ed0d020e9b0439041222de3e7f https://doi.org/10.1021/jo0263667 Zobrazit plný text záznamu