Reactions of Bis(p-methoxyphenyl)trisulfane and Its Oxides with Dimethyldioxirane and (Trifluoromethyl)methyldioxirane

Autor:	Edward L. Clennan, Kristina L. Stensaas
Rok vydání:	1996
Předmět:	Trisulfane chemistry.chemical_compound Trifluoromethyl Chemistry Organic Chemistry Proton NMR Organic chemistry Dimethyldioxirane Medicinal chemistry Decomposition
Zdroj:	The Journal of Organic Chemistry. 61:7911-7917
ISSN:	1520-6904 0022-3263
Popis:	The reactions of dimethyldioxirane and (trifluoromethyl)methyldioxirane with bis(p-methoxyphenyl)trisulfane, its 1-oxide, its 2-oxide, and its 1,1-dioxide derivatives have been investigated. The reactions were followed by careful monitoring of the methoxy region of the (1)H NMR spectra and where possible by doping with authentic samples of the products. The decomposition of labile intermediates and products was investigated. A new mechanism for the rearrangement of a trisulfane 1,3-dioxide to a trisulfane 1,1-dioxide is proposed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::da82fe5494b0394b55b8529b46c6d9d3 https://doi.org/10.1021/jo960995x Zobrazit plný text záznamu