4H-1,2,6-Thiadiazin-4-one-containing small molecule donors and additive effects on their performance in solution-processed organic solar cells
| Autor: | Hermerschmidt, F., Kalogirou, Andreas S., Min, J., Zissimou, Georgia A., Tuladhar, S. M., Ameri, T., Faber, H., Itskos, Grigorios, Choulis, Stelios A., Anthopoulos, T. D., Bradley, D. D. C., Nelson, J., Brabec, C. J., Koutentis, Panayiotis Andreas |
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| Přispěvatelé: | Itskos, Grigorios [0000-0003-3971-3801], Koutentis, Panayiotis Andreas [0000-0002-4652-7567], Zissimou, Georgia A. [0000-0003-4821-9469], Kalogirou, Andreas S. [0000-0002-5476-5805], Choulis, Stelios A. [0000-0002-7899-6296] |
| Rok vydání: | 2015 |
| Předmět: |
Solar cells
Systematic variation Electron mobility Fullerene Materials science Organic solar cell Technische Fakultät Silicones Bulk heterojunction solar cells Hole mobility Power conversion efficiencies Polymer solar cell Solution-processed Materials Chemistry Side chain Organic chemistry Alkyl chemistry.chemical_classification Energy conversion efficiency Donor acceptor donors technology industry and agriculture General Chemistry Electrical Engineering - Electronic Engineering - Information Engineering Acceptor Alkyl side chains Polydimethylsiloxane PDMS chemistry Chemical engineering Heterojunctions Engineering and Technology Fullerenes ddc:600 |
| Zdroj: | Journal of Materials Chemistry C J.Mater.Chem.C |
| ISSN: | 2050-7534 2050-7526 |
| DOI: | 10.1039/c4tc02931c |
| Popis: | The optical, electrochemical, morphological and transport properties of a series of thiadiazinone (acceptor) and (thienyl)carbazoles (donor) containing π-extended donor-acceptor-donors (D-A-D) are presented. Systematic variations in the number of the thienyl units, the choice of branched or straight alkyl side chains and the use of a processing additive demonstrate their use as electron donors in bulk heterojunction solar cells blended with fullerene acceptors. The best power conversion efficiency (PCE) of 2.7% is achieved by adding to the D-A-D 3:fullerene blend a polydimethylsiloxane (PDMS) additive, that improves the morphology and doubles the hole mobility within the D-A-D:fullerene blend. © The Royal Society of Chemistry. 3 10 2358 2365 Cited By :7 |
| Databáze: | OpenAIRE |
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