Sustainability of cellulose dissolution and regeneration in 1,5-diazabicyclo[4.3.0]non-5-enium acetate: a batch simulation of the IONCELL-F process
| Autor: | Ronny Wahlström, Anna Suurnäkki, Stella Rovio, Uula Hyväkkö, Arno Parviainen, Ilkka Kilpeläinen, U. Liimatainen, Alistair W. T. King, Tiina Liitiä, Jussi Helminen |
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| Přispěvatelé: | Department of Chemistry |
| Jazyk: | angličtina |
| Rok vydání: | 2015 |
| Předmět: |
EXTRACTION
General Chemical Engineering 116 Chemical sciences Cellulase PRETREATMENT engineering.material ENZYMATIC-HYDROLYSIS BIOMASS chemistry.chemical_compound Hydrolysis SACCHARIFICATION Enzymatic hydrolysis Cellulose WHEAT-STRAW Dissolution ta116 ta215 RICE STRAW Chromatography biology IDENTIFICATION Pulp (paper) General Chemistry 6. Clean water Solvent chemistry Ionic liquid engineering biology.protein DISSOLVING IONIC LIQUIDS CHROMOPHORES Nuclear chemistry |
| Zdroj: | Parviainen, A, Wahlström, R, Liimatainen, U, Liitiä, T, Rovio, S, Helminen, J K J, Hyväkkö, U, King, A W T, Suurnäkki, A & Kilpeläinen, I 2015, ' Sustainability of cellulose dissolution and regeneration in 1,5-diazabicyclo[4.3.0]non-5-enium acetate: a batch simulation of the IONCELL-F process ', RSC Advances, vol. 5, pp. 69728-69737 . https://doi.org/10.1039/C5RA12386K |
| ISSN: | 2046-2069 |
| DOI: | 10.1039/C5RA12386K |
| Popis: | The recyclability of 1,5-diazabicyclo[4.3.0] non-5-enium acetate ([DBNH][OAc]), as a direct dissolution solvent for cellulose, was evaluated during laboratory scale recycling trials. The main objective was to simulate the conditions of a spinning bath from a Lyocell-type air-gap spinning process, called the IONCELL-F process. The saline solution was then concentrated, recycled and reused as many times as possible before cellulose dissolution was no longer possible. The chemical compositions of the ionic liquid and pulp were recorded throughout the experiments. The results of the experiments showed that [DBNH][OAc] can be recycled from aqueous media with an average recovery rate of 95.6 wt% using basic laboratory equipment, without any further process intensification or optimisation. The recycling of the ionic liquid did not change the chemical composition or degree of polymerisation of the recovered pulp but the colour of the regenerated pulps gradually darkened as the recycling times increased. The ionic liquid was found to hydrolyse 6.0-13.6 mol% per cycle, under these conditions. The build-up of the hydrolysis product, 3-( aminopropyl)-2-pyrrolidonium acetate, killed the dissolution feature at between 30.6-45.6 wt% hydrolysis product. The enzymatic digestibility of the regenerated pulp samples was studied with both a monocomponent endoglucanase and a cellulase mixture. The amount of residual [DBNH][OAc] in the regenerated pulps was determined, by both NMR and capillary electrophoresis. Although hydrolysis of the ionic liquid occurs, this study clearly shows potential for industrial application, with appropriate process equipment and recycling conditions. |
| Databáze: | OpenAIRE |
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