A mesoporous Zr-based metal–organic framework driven by the assembly of an octatopic linker

Autor:	Borja Ortín-Rubio, Cristina Perona, José A. Suárez del Pino, Francisco J. Carmona, Felipe Gándara, Jorge A R Navarro, Judith Juanhuix, Inhar Imaz, Daniel Maspoch
Jazyk:	angličtina
Rok vydání:	2023
Předmět:	Materials Chemistry Metals and Alloys Ceramics and Composites General Chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials
Popis:	Metal–organic frameworks (MOFs) based on high-connected nets are generally very attractive due to their combined robustness and porosity. Here, we describe the synthesis of BCN-348, a new high-connected Zr-MOF built from an 8-connected (8-c) cubic Zroxocluster and an 8-c organic linker. BCN-348 contains a minimal edge-transitive 3,4,8-c eps net, and combines mesoporosity with thermal and hydrolytic stability. Encouraging results from preliminary studies on its use as a catalyst for hydrolysis of a nerve-agent simulant suggest its potential as an agent for detoxification of chemical weapons and other pernicious compounds. European Union’s Horizon 2020 research and innovation programme, under grant agreement No 101019003 Catalan AGAUR (project 2021 SGR 00458) the CERCA Programme/Generalitat de Catalunya, and the Spanish MCIN/AEI/10.13039/501100011033 (Project PID2020-113608RB-I00 ICN2 is supported by the Severo Ochoa Centres of Excellence programme Grant CEX2021- 001214-S, funded by MCIN/AEI/10.13039.501100011033
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d9b33641d589f55b205f443dd141416e https://hdl.handle.net/10481/82918 Zobrazit plný text záznamu