A mesoporous Zr-based metal–organic framework driven by the assembly of an octatopic linker
| Autor: | Borja Ortín-Rubio, Cristina Perona, José A. Suárez del Pino, Francisco J. Carmona, Felipe Gándara, Jorge A R Navarro, Judith Juanhuix, Inhar Imaz, Daniel Maspoch |
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| Jazyk: | angličtina |
| Rok vydání: | 2023 |
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| Popis: | Metal–organic frameworks (MOFs) based on high-connected nets are generally very attractive due to their combined robustness and porosity. Here, we describe the synthesis of BCN-348, a new high-connected Zr-MOF built from an 8-connected (8-c) cubic Zroxocluster and an 8-c organic linker. BCN-348 contains a minimal edge-transitive 3,4,8-c eps net, and combines mesoporosity with thermal and hydrolytic stability. Encouraging results from preliminary studies on its use as a catalyst for hydrolysis of a nerve-agent simulant suggest its potential as an agent for detoxification of chemical weapons and other pernicious compounds. European Union’s Horizon 2020 research and innovation programme, under grant agreement No 101019003 Catalan AGAUR (project 2021 SGR 00458) the CERCA Programme/Generalitat de Catalunya, and the Spanish MCIN/AEI/10.13039/501100011033 (Project PID2020-113608RB-I00 ICN2 is supported by the Severo Ochoa Centres of Excellence programme Grant CEX2021- 001214-S, funded by MCIN/AEI/10.13039.501100011033 |
| Databáze: | OpenAIRE |
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