Luminescent assemblies of pyrene-containing bent-core mesogens: liquid crystals, π-gels and nanotubes
| Autor: | Marta Martínez-Abadía, Shinto Varghese, Johannes Gierschner, Raquel Giménez, M. Blanca Ros |
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| Přispěvatelé: | Ministerio de Ciencia, Innovación y Universidades (España), Agencia Estatal de Investigación (España), Ministerio de Economía y Competitividad (España), Gobierno de Aragón, European Commission, Consejo Superior de Investigaciones Científicas (España), Campus de Excelencia Internacional UAM+CSIC, Universidad de Zaragoza |
| Rok vydání: | 2022 |
| Předmět: | |
| Zdroj: | Repositorio Institucional del Instituto Madrileño de Estudios Avanzados en Nanociencia instname Digital.CSIC. Repositorio Institucional del CSIC |
| Popis: | Bent-shaped molecules incorporating terminal pyrene moieties were designed and synthesized aiming at promoting a variety of luminescent self-assembled materials. The novel compounds are fluorescent both in solution and in condensed phases, achieving brighter fluorescence in the last case with fluorescence quantum yields up to 60%. Depending on the number of pyrene units (1 or 2) and/or the presence or absence of a long and flexible linker between the bent-core and the pyrene structures, bent-core liquid crystal phases, physical gels and nanoassemblies were obtained. Their properties depend on the molecular design, unveiling a synergistic and versatile 'tandem' of the bi-functional system in supramolecular functional materials chemistry. Long hydrocarbon spacers connecting bent-core and pyrene structures were necessary to display mesomorphic properties, achieving monotropic rectangular columnar mesophases, being for one compound stable at room temperature and displaying a glassy transition below room temperature, as revealed by POM, DSC and XRD. Liquid crystal phases exhibited excimer-like emission. In addition, organogels were obtained without the help of hydrogen bonding functionalities, exhibiting in one case supergelator behavior. Different nanoassemblies were obtained from these non-amphiphilic bent-core structures, in particular unprecedented organic nanotubes with beveled ends formed by a single bilayer. The authors from INMA greatly appreciate financial support from projects of the Spanish Government PGC2018-093761-B-C31 [MCIU/AEI/FEDER, UE] and MAT2015-66208-C3-1 [MINECO/FEDER, UE], the Gobierno de Aragón/FEDER (research group E47_20R) and the JAE.PREDOC-CSIC (M. M.-A.) fellowship program. Thanks are given to the nuclear magnetic resonance, mass spectrometry, and thermal analysis services of the INMA (Univ. Zaragoza-CSIC), the LMA (Univ. Zaragoza) for TEM images and Servicio General de Apoyo a la Investigación-SAI (Univ. Zaragoza) for SEM images. The work at IMDEA was supported by the Spanish Government (MINECO-FEDER project CTQ2017-87054, MICINN project CEX2020-001039-S) and by the Campus of International Excellence (CEI) UAM+CSIC. |
| Databáze: | OpenAIRE |
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