Fixing carbon dioxide with copper: crystal structure of [LCu(mu-C2O4)CuL][Ph4B]2 (L = N,N',N'-triallyl-1,4,7-triazacyclononane)

Autor:	Stefan Lopinski, Louis J. Farrugia, Paul A. Lovatt, Robert D. Peacock
Rok vydání:	2001
Předmět:	Inorganic Chemistry chemistry.chemical_compound Chemistry Sodium Inorganic chemistry Carbon dioxide Oxalate anion chemistry.chemical_element Methanol Crystal structure Physical and Theoretical Chemistry Copper Nuclear chemistry
Zdroj:	Inorganic chemistry. 40(3)
ISSN:	0020-1669
Popis:	Reaction of CuI, 1,4,7-triallyl-triazacyclononane (L), and sodium tetraphenylboron with either CsHCO3 in dry methanol or CO2 in slightly moist methanol results in the formation of the oxalate anion, which is isolated as [LCu(μ-C2O4)CuL][Ph4B]2 (1).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d96f88457a5a73b9708f6ce5fced50b8 https://pubmed.ncbi.nlm.nih.gov/11209617 Zobrazit plný text záznamu