Chirality-dependent balance between hydrogen bonding and London dispersion in isolated (±)-1-indanol clusters
| Autor: | Aude Bouchet, Jonas Altnöder, Juhyon J. Lee, Anne Zehnacker-Rentien, Katharina E. Otto, Martin A. Suhm |
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| Rok vydání: | 2013 |
| Předmět: |
010405 organic chemistry
Chemistry Hydrogen bond hydrogen bonding London dispersion 1-indanol General Physics and Astronomy Infrared spectroscopy 010402 general chemistry 01 natural sciences London dispersion force 0104 chemical sciences Ion symbols.namesake chemistry.chemical_compound Enantiopure drug Computational chemistry Chemical physics symbols Physical and Theoretical Chemistry Fourier transform infrared spectroscopy Homology (chemistry) Raman scattering |
| Zdroj: | Physical chemistry chemical physics : PCCP. 15(25) |
| ISSN: | 1463-9084 |
| Popis: | The aggregation behavior of racemic and enantiopure 1-indanol has been studied by FTIR spectroscopy, resonant ion dip IR spectroscopy, and spontaneous Raman scattering in supersonic jets. This triple experimental approach, augmented by homology to related molecular fragments and dispersion-corrected DFT predictions, allows disentangling the complex spectroscopic signature in the OH stretch range. Evidence for chirality-sensitive aggregation via isolated OH···π bonds in competition with cooperative ···OH···OH···π patterns is collected. An accurate description of London dispersion forces provides the key to its explanation. peerReviewed |
| Databáze: | OpenAIRE |
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