Identification of the products of partial hydrolysis of silicon tetrafluoride by matrix isolation IR spectroscopy
| Autor: | Otto Schrems, Peter Sennikov, Stanislav K. Ignatov |
|---|---|
| Rok vydání: | 2010 |
| Předmět: |
Partial hydrolysis
Materials Science (miscellaneous) Matrix isolation Analytical chemistry Infrared spectroscopy 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Inorganic Chemistry chemistry.chemical_compound symbols.namesake Fourier transform chemistry Silicon tetrafluoride symbols Physical and Theoretical Chemistry 0210 nano-technology |
| Zdroj: | EPIC3Russian Journal of Inorganic Chemistry, 55(3), pp. 413-420, ISSN: 0036-0236 |
| ISSN: | 1531-8613 0036-0236 |
| DOI: | 10.1134/s0036023610030198 |
| Popis: | Matrix isolation Fourier transform IR spectroscopy has been used for studying the products and mechanism of the silicon tetrafluoride reaction with water at various component ratios and reaction durations. Assignment of new bands in the spectrum confirms the earlier assumptions of first the formation of a molecular complex with water and later of trifluorosilanol, which finally condenses to give hexafluorodisiloxane. |
| Databáze: | OpenAIRE |
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