Analytical response of polychlorinated biphenyl homologues and isomers in thin-layer and gas chromatography
| Autor: | Frederick D. Baker, R. dell'Acqua, C.L. Houck, Brian Bush, Fa-chun Lo |
|---|---|
| Rok vydání: | 1975 |
| Předmět: |
Residue (complex analysis)
Chromatography Chromatography Gas Electron capture Organic Chemistry Thin layer Statistics as Topic Polychlorinated biphenyl Electrons General Medicine Biochemistry Polychlorinated Biphenyls Mass Spectrometry Analytical Chemistry chemistry.chemical_compound chemistry Yield (chemistry) Methods Gas chromatography Chromatography Thin Layer Estimation methods |
| Zdroj: | Journal of chromatography. 109(2) |
| Popis: | Except for pure synthetic polychlorinated biphenyl (PCB), estimation methods of PCB by thin-layer and gas chromatography with electron capture detection give comparable results. Both gives a good estimate of the true mass of a biologically modified residue, but where mostly hexachlorobiphenyls and above make up the residue, the estimate will be up to 50% too high. The Coulson detector does not, in our hands, yield comparable results with modified residues; the reason for this diffuse is not clear at present. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|