Synthesis and physicochemical characterization of pyrrolidinium based surfactants
| Autor: | Alessandra Muschietti, Maria Grazia Bonicelli, Claudio Sperduto, Giovanna Mancini, Marco Ierino, Alessandra Bartoloni, Luciano Galantini, Cecilia Bombelli, Stefano Borocci, Luisa Giansanti |
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| Rok vydání: | 2012 |
| Předmět: |
Pyrrolidines
Mixed cationic liposomes Charge exposure DSC Fluorescence Phase segregation Pyrrolidinium based surfactants Chemistry Physical Molecular Structure Surface-Active Agents Surfaces Coatings and Films Electronic Optical and Magnetic Materials Biomaterials Colloid and Surface Chemistry charge exposure mixed cationic liposomes fluorescence pyrrolidinium based surfactants dsc phase segregation Thermotropic crystal Coatings and Films Differential scanning calorimetry Amphiphile Physical Electronic Organic chemistry Molecule Optical and Magnetic Materials Alkyl chemistry.chemical_classification Liposome Vesicle Cationic polymerization Surfaces Chemistry chemistry Chemical engineering lipids (amino acids peptides and proteins) |
| Zdroj: | Journal of colloid and interface science 392 (2013): 297–303. doi:10.1016/j.jcis.2012.09.065 info:cnr-pdr/source/autori:A. Bartoloni, C. Bombelli, S. Borocci, M. G. Bonicelli, L. Galantini,L. Giansanti, M. Ierino, G. Mancini, A. Muschietti, C. Sperduto/titolo:Synthesis and physicochemical characterization of pyrrolidinium based surfactants/doi:10.1016%2Fj.jcis.2012.09.065/rivista:Journal of colloid and interface science (Print)/anno:2013/pagina_da:297/pagina_a:303/intervallo_pagine:297–303/volume:392 |
| ISSN: | 1095-7103 |
| Popis: | Three new pyrrolidinium based surfactants were synthesized and characterized as pure aggregate components and in mixtures with 1,2-dimyristoyl-sn-glycero-3-phosphocholine to understand how the molecular structure of the cationic amphiphile and its mole percentage might affect the physicochemical properties of the resulting aggregates. The thermotropic behavior of the mixed liposomes was investigated by differential scanning calorimetry on multilamellar vesicles, whereas their size and surface potential were investigated on large unilamellar vesicles by dynamic laser light scattering and fluorescence experiments, respectively. The presence of either methoxy or hydroxy groups in the positions 3 and 4 of the pyrrolidinium ring as well as the presence of a second alkyl chain on pyrrolidinium nitrogen, controls the aggregates features. |
| Databáze: | OpenAIRE |
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