Synthesis of novel water-soluble sulfonated cellulose
| Autor: | Dash Rajalaxmi, Gelbaum Leslie, Arthur J. Ragauskas, Nan Jiang |
|---|---|
| Rok vydání: | 2010 |
| Předmět: |
Magnetic Resonance Spectroscopy
engineering.material Sulfonic acid Biochemistry Analytical Chemistry chemistry.chemical_compound Organic chemistry Cellulose Solubility chemistry.chemical_classification Sodium periodate Pulp (paper) Periodic Acid Organic Chemistry Water Periodate General Medicine chemistry Kraft process Sodium bisulfite Microscopy Electron Scanning engineering Sulfonic Acids Oxidation-Reduction Nuclear chemistry |
| Zdroj: | Carbohydrate Research. 345:284-290 |
| ISSN: | 0008-6215 |
| DOI: | 10.1016/j.carres.2009.09.037 |
| Popis: | Water-soluble sulfonated cellulose (SC) samples were synthesized by oxidizing hardwood kraft pulp with sodium periodate followed by the sulfonation reaction with sodium bisulfite. Six levels of oxidation/sulfonation were obtained by using different mmols (0.93-4.67) of periodate per gram of pulp. The aldehyde and sulfonic acid contents, surface morphology, and water solubility property of these treated fibers were characterized. It was found that carbonyl group content increased with the periodate charge and so did the sulfonic acid content in subsequent sulfonation step. Scanning electron microscopy images showed a significant change in surface morphology of the sulfonated samples. Solubility of sulfonated cellulose in water was determined from (1)H NMR spectra and a solubility of 28.57 g/L was found when cellulose was oxidized with 4.67 mmol periodate per gram cellulose followed by the sulfonation reaction. |
| Databáze: | OpenAIRE |
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