Cardanol‐Based Epoxy Monomers for High Thermal Properties Thermosets
| Autor: | Mélanie Decostanzi, Sylvain Caillol, Anne-Sophie Mora, Ghislain David |
|---|---|
| Přispěvatelé: | Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier (ICGM ICMMM), Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM)-Centre National de la Recherche Scientifique (CNRS)-Université de Montpellier (UM)-Université Montpellier 1 (UM1)-Université Montpellier 2 - Sciences et Techniques (UM2)-Institut de Chimie du CNRS (INC) |
| Rok vydání: | 2019 |
| Předmět: |
Materials science
030309 nutrition & dietetics Thermosetting polymer Epoxide epoxy Industrial and Manufacturing Engineering biobased polymer 03 medical and health sciences chemistry.chemical_compound 0404 agricultural biotechnology Thermal cardanol ComputingMilieux_MISCELLANEOUS Curing (chemistry) 0303 health sciences Cardanol 04 agricultural and veterinary sciences General Chemistry Epoxy 040401 food science [CHIM.POLY]Chemical Sciences/Polymers Monomer chemistry Chemical engineering visual_art visual_art.visual_art_medium Food Science Biotechnology |
| Zdroj: | European Journal of Lipid Science and Technology European Journal of Lipid Science and Technology, Wiley-VCH Verlag, 2019, 121 (8), pp.1800421-1800428. ⟨10.1002/ejlt.201800421⟩ |
| ISSN: | 1438-9312 1438-7697 |
| DOI: | 10.1002/ejlt.201800421 |
| Popis: | In this paper, epoxy‐anhydride networks are synthesized from a new product of Cardolite Corporation: the Cardolite GX‐2551 epoxy monomer. Due to the complexity of the GX‐2551 structure, an NMR study is performed first to characterize this new commercial product. This epoxy monomer is then reacted with an anhydride (MHHPA) to form polyepoxide thermosets. After curing, dynamic mechanical and thermal analyses are performed for the different thermosets, and then the results are compared to each other. Practical Applications: The cardanol‐derived epoxy monomer described in this contribution, i.e., fully epoxidized molecular cardanol, is a new fully biobased monomer for further epoxy thermoset synthesis. The resulting polyepoxide networks exhibit much higher thermo‐mechanical properties than previous cardanol‐derived epoxy thermosets. Two cardanol‐based epoxy monomers are fully characterized. The GX2551 is reported for the first time and exhibits a higher renewable carbon content. Both monomers are reacted with hexahydro‐4‐methylphtalic anhydride to yield bio‐based aromatic polyepoxide networks with interesting mechanical and thermal properties. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|