Molecular chirality: A new approach from a dynamical point of view
| Autor: | Eizi Hirota |
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| Rok vydání: | 2017 |
| Předmět: |
Models
Molecular Physics asymmetric syntheses Internal rotation chiral molecule General Physics and Astronomy Stereoisomerism Chemistry Techniques Synthetic General Medicine Inversion (discrete mathematics) low-frequency mode Quantum mechanics Original Article Point (geometry) double minimum potential Organic Chemicals Enantiomer General Agricultural and Biological Sciences Chirality (chemistry) |
| Zdroj: | Proceedings of the Japan Academy. Series B, Physical and Biological Sciences |
| ISSN: | 1349-2896 0386-2208 |
| Popis: | The double minimum potential (DMP), which Hund assumed to explain the quantum-mechanical stability of enantiomers, was discussed, by citing three typical examples of DMP: inversion, internal rotation, and puckering. They expanded the classical scope of chirality, as defined by Kelvin, and indicated that a new bridge could be formed between the three low-frequency DMP modes and the asymmetric syntheses of chiral molecules. |
| Databáze: | OpenAIRE |
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