Phosphorus pentoxide as a cost-effective, metal-free catalyst for ring opening polymerization of ε-caprolactone
| Autor: | Abdel Khoukh, Redouane Beniazza, Ismail Adoumaz, Abdelkrim El Kadib, Mohammed Lahcini, Hicham Qayouh, El Hassan Boutriouia, Maud Save |
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| Přispěvatelé: | Université Cadi Ayyad [Marrakech] (UCA), Institut des Sciences Moléculaires (ISM), Université Montesquieu - Bordeaux 4-Université Sciences et Technologies - Bordeaux 1-École Nationale Supérieure de Chimie et de Physique de Bordeaux (ENSCPB)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Mohammed VI Polytechnic University [Marocco] (UM6P), Euromed Research Center. Engineering Division [Fès], Université Euro Méditerranéenne de Fès (UEMF), Institut des sciences analytiques et de physico-chimie pour l'environnement et les materiaux (IPREM), Université de Pau et des Pays de l'Adour (UPPA)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Moroccan Ministry of Education and Research, Providence Health Care Toubkal/ 17/51–Campus France |
| Rok vydání: | 2020 |
| Předmět: |
General Chemical Engineering
02 engineering and technology 010402 general chemistry 01 natural sciences Ring-opening polymerization Catalysis Cost effectiveness chemistry.chemical_compound [CHIM.ANAL]Chemical Sciences/Analytical chemistry Polymer chemistry Nuclear magnetic resonance spectroscopy chemistry.chemical_classification Nanocomposite Catalysts General Chemistry Polymer [CHIM.MATE]Chemical Sciences/Material chemistry 021001 nanoscience & nanotechnology 0104 chemical sciences [CHIM.THEO]Chemical Sciences/Theoretical and/or physical chemistry Monomer [CHIM.POLY]Chemical Sciences/Polymers chemistry Polymerization 0210 nano-technology Caprolactone Phosphorus pentoxide |
| Zdroj: | RSC Advances RSC Advances, Royal Society of Chemistry, 2020, 10 (39), pp.23498-23502. ⟨10.1039/d0ra04251j⟩ |
| ISSN: | 2046-2069 |
| DOI: | 10.1039/d0ra04251j⟩ |
| Popis: | International audience; The ring-opening polymerization (ROP) of ϵ-caprolactone (ϵ-CL) using phosphorus pentoxide (P2O5) as a metal-free catalyst and isopropanol (iPrOH) as initiator resulted in the preparation of poly(ϵ-caprolactone) with narrow weight distribution. NMR spectroscopy analyses of the prepared PCL indicated the presence of the initiator residue at the end of the polymer chain, implying the occurrence of the ϵ-CL-catalysis ROP through a monomer activation mechanism. Kinetic experiments confirmed the controlled/living nature of ϵ-CL ring-opening catalyzed by phosphorus pentoxide. The commercial availability of phosphorus pentoxide and its easy-handling provide additional opportunities for polymer synthesis and nanocomposite manufacturing. T |
| Databáze: | OpenAIRE |
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