Hybrid silica nanoparticles for sequestration and luminescence detection of trivalent Rare Earth ions (Dy3+ and Nd3+) in solution
| Autor: | Seda Demirel Topel, Carmen Tiseanu, Vadim G. Kessler, Jean-Marie Nedelec, Gulaim A. Seisenbaeva, João Rocha, Elizabeth Polido Legaria |
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| Přispěvatelé: | Swedish University of Agricultural Sciences (SLU), National Institute for Lasers, Plasma, and Radiation Physics - INFLPR (ROMANIA), CICECO, Department of Chemistry, Universidade de Aveiro, Institut de Chimie de Clermont-Ferrand (ICCF), Université Blaise Pascal - Clermont-Ferrand 2 (UBP)-SIGMA Clermont (SIGMA Clermont)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS) |
| Jazyk: | angličtina |
| Rok vydání: | 2014 |
| Předmět: |
Lanthanide
Metal ions in aqueous solution Inorganic chemistry URANIUM EFFICIENT Bioengineering Hydrochloric acid Complexometric titration chemistry.chemical_compound Adsorption LANTHANIDE COMPLEXES [CHIM]Chemical Sciences General Materials Science EUROPIUM COMPLEXES Aqueous solution CRYSTAL General Chemistry FRAMEWORKS Condensed Matter Physics Atomic and Molecular Physics and Optics CARBOXYLATES MESOPOROUS SILICA chemistry Modeling and Simulation PHOTOLUMINESCENCE CHLORIDE Nanoadsorbents Surface grafting Trivalent rare-earth ions (RE) Heavy metal sequestration Luminescent probe Luminescence Hybrid material |
| Zdroj: | Journal of Nanoparticle Research Journal of Nanoparticle Research, Springer Verlag, 2014, 16, pp.2783. ⟨10.1007/s11051-014-2783-6⟩ Journal of Nanoparticle Research, 2014, 16, pp.2783. ⟨10.1007/s11051-014-2783-6⟩ Repositório Científico de Acesso Aberto de Portugal Repositório Científico de Acesso Aberto de Portugal (RCAAP) instacron:RCAAP |
| ISSN: | 1388-0764 1572-896X |
| DOI: | 10.1007/s11051-014-2783-6⟩ |
| Popis: | International audience; New hybrid material-based adsorbents acting also as luminescent probes upon uptake of trivalent rare-earth (RE) ions Nd3+ and Dy3+ have been developed. SiO2 NPs functionalized by three different organic ligands, N-aminopropylen-amido-iminodiacetic acid (L1), pyridine-α,β-dicarboxylic acid bis(propylenamide) (L2), and N-propylen-iminodiacetic acid (L3), have been produced and fully characterized by 13C, 1H, and 29Si solid-state NMR, FTIR, TGA, XRD, TEM, nitrogen gas adsorption, and also by NTA and DLS in solution. The synthesized hybrid materials are well dispersible and stable in aqueous solutions according to NTA and consist of spheres with diameters less than 100 nm. Their affinities to the lanthanide ions Dy3+ and Nd3+ have been investigated in aqueous solution and characterized by SEM–EDS and complexometric titration, demonstrating that they can be successfully used as adsorbents for sequestration of trivalent RE ions. The adsorbed RE ions can efficiently be desorbed from saturated nanoadsorbents by addition of hydrochloric acid. The produced nanomaterials may also be used as luminescent probes for Dy3+ and Nd3+ ions in solution. |
| Databáze: | OpenAIRE |
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