Structural transformations of bioactive glass 45S5 with thermal treatments

Autor: Alexandre Govin, Rachid Zenati, Jérôme Chevalier, Laurent Gremillard, Leila Lefebvre, D. Bernache-Assolant, G. Thollet
Přispěvatelé: Matériaux, ingénierie et science [Villeurbanne] (MATEIS), Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-Institut National des Sciences Appliquées de Lyon (INSA Lyon), Institut National des Sciences Appliquées (INSA)-Université de Lyon-Institut National des Sciences Appliquées (INSA)-Centre National de la Recherche Scientifique (CNRS)
Jazyk: angličtina
Rok vydání: 2007
Předmět:
Zdroj: Acta Materialia
Acta Materialia, Elsevier, 2007, pp.3305-3313
ISSN: 1359-6454
Popis: International audience; We report on the structural transformations of Bioglass® during thermal treatments. Just after the glassy transition, at 550 °C, a glassy phase separation occurs at 580 °C, with the appearance of one silicate- and one phosphate-rich phase. It is followed by the crystallization of the major phase Na2CaSi2O6, from 610 to 700 °C and of the secondary phase, silico-rhenanite, at 800 °C. The latter evolves from the phosphate-rich glassy phase, which is still present after the first crystallization. In order to control the processing of glass-ceramic products from Bioglass®, crystallization kinetics were studied via differential scanning calorimetry measurements in the range of 620-700 °C and temperature-time-transformation curves were established.
Databáze: OpenAIRE