Influence of step faceting on the enantiospecific decomposition of aspartic acid on chiral Cu surfaces vicinal to Cu{111}
| Autor: | Andrew J. Therrien, Timothy J. Lawton, Andrew J. Gellman, E. C. H. Sykes, R. Ali, Aaron Reinicker |
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| Rok vydání: | 2016 |
| Předmět: |
Chemistry
Metals and Alloys 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Decomposition Catalysis 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials Faceting Crystallography Adsorption Aspartic acid Materials Chemistry Ceramics and Composites Facet 0210 nano-technology Vicinal |
| Zdroj: | Chemical communications (Cambridge, England). 52(75) |
| ISSN: | 1364-548X |
| Popis: | On surfaces vicinal to Cu{111}, L-aspartic acid (L-Asp) adsorption causes steps to facet enantiospecifically into {310}R and {320}S steps. L-Asp has its highest heat of adsortion on surfaces that naturally expose the {310}R or {320}S steps but decomposes preferentially on the {310}R steps. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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